Triblock copolymer based thermoreversible gels. 1: Self-association of sPMMA end-blocks in o-xylene and viscoelasticity of the gels

Triblock copolymer based thermoreversible gels. 1: Self-association of sPMMA end-blocks in o-xylene and viscoelasticity of the gels

Syndiotactic poly(methyl methacrylate) (sPMMA)-polybutadiene (PBD)—sPMMA triblock copolymers, or MBM, have been studied in the presence of o-xylene which is a selective solvent for the central PBD block. Syndiotactic PMMA is known to self associate in o-xylene. The central PBD sequence does not prevent the selfassociation of sPMMA from occurring. Actually, this phenomenon contributes to the sta...

Silica reinforced triblock copolymer gels

The effect of silica and polymer coated silica particles as reinforcing agents on the structural and mechanical properties of polystyrene–poly(ethylene/butylene)–polystyrene (PS–PEB–PS) triblock gel has been investigated. Different types of chemically modified silica have been compared in order to evaluate the influence of the compatibility between gel and filler. Time-resolved SANS and small-a...

Disulfide-Based Diblock Copolymer Worm Gels: A Wholly-Synthetic Thermoreversible 3D Matrix for Sheet-Based Cultures.

It is well-known that 3D in vitro cell cultures provide a much better model than 2D cell cultures for understanding the in vivo microenvironment of cells. However, significant technical challenges in handling and analyzing 3D cell cultures remain, which currently limits their widespread application. Herein, we demonstrate the application of wholly synthetic thermoresponsive block copolymer worm...

the relationship between academic self-concept and academic achievement in english and general subjects of the students of high school

according to research, academic self-concept and academic achievement are mutually interdependent. in the present study, the aim was to determine the relationship between the academic self-concept and the academic achievement of students in english as a foreign language and general subjects. the participants were 320 students studying in 4th grade of high school in three cities of noor, nowshah...

Liquid Crystalline Gels by Self-Assembly of Triblock Copolymers